For soaring bridges, dramatic skyscrapers and even the path around your local park, builders love concrete, making it the most-used building material in the world – but producing the cement used in most concrete accounts for eight per cent of global greenhouse gas emissions.
The construction industry is desperate for a cleaner solution, with both startups and manufacturing giants developing ways to slash emissions, but the nature of the material and how it's made means net-zero concrete may not be possible.
Concrete is made from materials such as sand, rocks and aggregate glued together by cement, and for the last 200 hundred years that's largely meant Portland cement, an English invention that changed how we build. But there's a problem: to produce Portland cement, limestone is heated to 1,450 degrees Celsius, sparking a chemical reaction that drops a carbon dioxide molecule from the limestone, also called calcium carbonate.
"The inherent chemical reactions in this process release huge amounts of carbon dioxide – there's no way to get away from that," says Brant Walkley, lecturer in chemical engineering at University of Sheffield. He adds that half of the emissions from producing cement come from this process. "For every molecule of limestone that is used to make Portland cement, a molecule of carbon dioxide is released."
One solution is to add supplementary materials, such as blast-furnace slag from steel production, fly ash from coal power plants, silica fume, calcined clays and other industrial wastes. Not only does that keep these wastes and byproducts out of landfill, but it means less cement is needed, slashing emissions by as much as half.
Cement can also be made without limestone. Alternatives such as geopolymers and calcium sulphoaluminate don't drop off that damaging carbon molecule, says Kevin Paine, professor at the University of Bath, but there's less of the necessary raw materials around the world. "None of them can be made at the scale we currently need," he says. Plus, switching production systems is expensive for the industry, meaning progress has been slow.
That means we can't yet – if ever – entirely ditch Portland cement, but there are other ways to reduce its impact. Canadian startup CarbonCure Technologies injects carbon dioxide into concrete while mixing it, not only trapping the gas but reducing the volume of cement required. "Once injected, the CO2 chemically converts into a mineral, which permanently eliminates the CO2 and actually improves the concrete’s compressive strength," says Dean Forgeron, vice president of engineering. The technique shaves off up to six per cent in emissions, the company says, saving 125 tonnes of CO2 when making a mid-rise building.
Luigi Di Sarno, of the Resilient and Sustainable Infrastructure group at the University of Liverpool, argues that clever design could reduce the need for maintenance and replacement of concrete in buildings, bridges and water-logged infrastructure such as flood defence walls, helping to slash carbon emissions. His self-healing concrete, called BIOCOREWALLS, patches cracks using bacteria that produces limestone when it comes into contact with water, extending the life of infrastructure built with concrete by 30 per cent.
Tweaked recipes, cement alternatives, carbon curing and self-healing designs will all help, but reducing our use of concrete in the first place could be the simplest way to slash emissions. Bridges, skyscrapers and nuclear power plants require concrete, but why are we using this precision-engineered material to make footpaths or retaining walls? "If we optimise its use, that will improve its sustainability, because you're not wasting that performance and creating CO2 emissions that weren't necessary," says Walkley.
Sources: wired.co.uk, dailyadvent.com
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